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Sensing the chirality of various organic solvents by helically arranged π-blades
Yuki Shimizu1, Yoshiaki Shoji, Daisuke Hashizume
1Laboratory for Chemistry and Life Science, Institute of Innovative Research, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan. yshoji@res.titech.ac.jp fukushima@res.titech.ac.jp.
Abstract:
Although the chiral enrichment of dynamic prochiral molecules usually requires a strong interaction with a chiral source, the enantiomer ratio of a propeller-shaped molecule, obtained by a recently developed boron-mediated benzannulation reaction of alkynes, is biased in various organic solvents through solvation for the propeller moieties.
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