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Synthesis of meso-Tetraaryl Triphyrins(2.1.1)
Kamakshya Nath Panda1, Kishor G Thorat1, Mangalampalli Ravikanth1
1Department of Chemistry , Indian Institute of Technology Bombay , Powai, Mumbai 400076 , India.
Abstract:
A simple, straightforward [2+1] condensation of 5,6-diaryldipyrroethene dicarbinols with pyrrole under mild acid-catalyzed conditions resulted in the formation of highly desirable aromatic β-free meso-tetraaryl [14]triphyrins(2.1.1) in 15-18% yields. The triphyrins(2.1.1) are very novel monoanionic tridentate ligands that form metal complexes readily as demonstrated here by preparing Re(I) complexes.
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