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Updated: Feb 5, 2026

Author Spotlight: Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers
Published on: May 12, 2023
Phosphine oxide-based tricarbonylrhenium(i) complexes from phosphine/phosphine oxide and dihydroxybenzoquinones
Ramar Arumugam1, Bhaskaran Shankar, Ramasamy Shanmugam
1Department of Chemistry, Thiagarajar College, Madurai 625 009, Tamil Nadu, India.
Abstract:
Neutral phosphine oxide (P[double bond, length as m-dash]O) donor-based organometallic complexes [{Re(CO)3O[double bond, length as m-dash]PCy3}{μ-DHBQ}{Re(CO)3O[double bond, length as m-dash]PCy3}] (1), [{Re(CO)3O[double bond, length as m-dash]PPh3}{μ-DHBQ}{Re(CO)3O[double bond, length as m-dash]PPh3}] (2), [{Re(CO)3O[double bond, length as m-dash]PCy3}{μ-THQ}{Re(CO)3O[double bond, length as m-dash]PCy3}] (3), [{Re(CO)3O[double bond, length as m-dash]PPh3}{μ-THQ}{Re(CO)3O[double bond, length as m-dash]PPh3}] (4), [{Re(CO)3O[double bond, length as m-dash]PCy3}{μ-CA}{Re(CO)3O[double bond, length as m-dash]PCy3}] (5), and [{Re(CO)3O[double bond, length as m-dash]PPh3}{μ-CA}{Re(CO)3O[double bond, length as m-dash]PPh3}] (6) were assembled from phosphine/phosphine oxide, a dihydroxybenzoquinone donor and Re2(CO)10via a one-pot solvothermal approach. The soft phosphine donor was transformed into a hard phosphine oxide donor during the formation of 1, 3, 4, 5, and 6. The complexes 1-6 were air and moisture stable and were soluble in polar organic solvents. The complexes were characterized by elemental analysis, FT-IR, and NMR spectroscopic methods. The molecular structures of 1, 2, 4, and 6 were analyzed by single-crystal X-ray diffraction analysis. The UV-Visible absorption studies indicated that 1-6 in THF display strong visible light absorption in the range of ∼350-700 nm.
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