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Updated: Feb 4, 2026

Flame Experiments at the Advanced Light Source: New Insights into Soot Formation Processes
Published on: May 26, 2014
Soot reduction by addition of dimethyl carbonate in normal and inverse ethylene diffusion flames: Nanostructural
Chutikarn Paladpokkrong1, Dong Liu1, Yaoyao Ying1
1MIIT Key Laboratory of Thermal Control of Electronic Equipment, School of Energy and Power Engineering, Nanjing University of Science & Technology, Nanjing 210094, China; Advanced Combustion Laboratory, School of Energy and Power Engineering, Nanjing University of Science & Technology, Nanjing 210094, China.
Abstract:
Oxygenated fuel represents an attractive alternative as an additive for reducing soot emissions. Dimethyl carbonate (DMC) is an oxygenated compound which is a good option to reduce soot, but the detailed characteristics of soot produced from combustion of hydrocarbon fuels blended with DMC are still lacking. The present research studied the nanostructure and reactivity of soot particles in ethylene/DMC normal and inverse diffusion flames. High resolution transmission electron microscopy (HRTEM), X-ray diffraction (XRD), and thermogravimetric analysis (TGA) were used to analyze the nanostructure and reactivity of soot. It was found that DMC addition was effective in decreasing the average weights of soot formed in flames. The results of HRTEM images showed that soot particles obtained with DMC addition showed liquid-like material and tight bonding, and exhibited more highly disorganized layers, which give it higher reactivity than soot obtained without DMC addition. Furthermore, HRTEM was used to analyze soot fringe characteristics consisting of fringe tortuosity, fringe length, and fringe separation. XRD was used to crosscheck the results for fringe separation, and was consistent with HRTEM results. In addition, the mass loss curve of TGA experiments showed that DMC addition could enhance the reactivity of soot particles.
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