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A degradable fluorinated surfactant for emulsion polymerization of vinylidene fluoride
Sanjib Banerjee1, Judith Schmidt, Yeshayahu Talmon
1Department of Chemistry, Indian Institute of Technology Bhilai, Raipur 492015, Chhattisgarh, India. sanjib.banerjee@iitbhilai.ac.in.
Abstract:
An original degradable fluorinated surfactant, 3-hydroxy-2-(trifluoromethyl)propanoic acid (MAF-OH), was applied for the emulsion polymerization of vinylidene fluoride (VDF) to yield a latex of PVDF, consisting of typically 100 nm particle diameters. This surfactant was shown to be easily decomposed in subcritical water, releasing fluoride anions. The % reversed head-to head (H-H) addition is greatly minimized (2.4%) in the PVDF, prepared in the presence of MAF-OH surfactant.
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