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Three-electrode Coin Cell Preparation and Electrodeposition Analytics for Lithium-ion Batteries
Published on: May 22, 2018
Bismuth germanate (Bi4Ge3O12), a promising high-capacity lithium-ion battery anode
Jassiel R Rodriguez1, Carlos Belman-Rodriguez, Sergio A Aguila
1Forney Hall of Chemical Engineering Purdue University West Lafayette, IN 47907, USA. vpol@purdue.edu.
Abstract:
An unexplored promising lithiation-host anode material, Bi4Ge3O12, delivers a reversible specific discharge capacity of ∼586 mA h g-1 at 200 mA g-1 after 500 cycles with a coulombic efficiency of ∼99.8%. DFT calculations detected distorted [BiO6]9- octahedra, and the band structure of BGO revealed an indirect gap of 3.50 eV. A plausible reaction mechanism of storing lithium is proposed.
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