Yb₂O₃ Doped Zr_0.92Y_0.08O_2-α(8YSZ) and Its Composite Electrolyte for Intermediate Temperature Solid Oxide Fuel Cells

Yb³⁺ and Y³⁺ double doped ZrO₂ (8YSZ+4Yb₂O₃) samples were synthesized by a solid state reaction method. Moreover, 8YSZ+4Yb₂O₃-NaCl/KCl composites were also successfully produced at different temperatures. The 8YSZ+4Yb₂O₃, 8YSZ+4Yb₂O₃-NaCl/KCl (800 °C), and 8YSZ+4Yb₂O₃-NaCl/KCl (1000 °C) samples were characterized by x⁻ray diffraction (XRD) and scanning electron microscopy (SEM). The results showed that a dense composite electrolyte was formed at a low temperature of 800 °C. The maximum conductivities of 4.7 × 10^-2 S·cm^-1, 6.1 × 10^-1 S·cm^-1, and 3.8 × 10^-1 S·cm^-1 were achieved for the 8YSZ+4Yb₂O₃, 8YSZ+4Yb₂O₃-NaCl/KCl (800 °C), and 8YSZ+4Yb₂O₃-NaCl/KCl (1000 °C) samples at 700 °C, respectively. The logσ~log (pO₂) plot result showed that the 8YSZ+4Yb₂O₃-NaCl/KCl (800 °C) composite electrolyte is a virtually pure ionic conductor. An excellent performance of the 8YSZ+4Yb₂O₃-NaCl/KCl (800 °C) composite was obtained with a maximum power density of 364 mW·cm^-2 at 700 °C.