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A Method for Selecting Structure-switching Aptamers Applied to a Colorimetric Gold Nanoparticle Assay
Published on: February 28, 2015
Nonaqueous Microemulsion in the Bmim Tf2N/Brij 30/ n-Nonane System: Structural Investigation and Application as Gold
Marianna Mamusa1, Marcia C Arroyo1, Emiliano Fratini1
1Department of Chemistry "Ugo Schiff" and CSGI , University of Florence , via della Lastruccia 3 , Sesto Fiorentino, 50019 Florence , Italy.
Abstract:
Microemulsions based on ionic liquids (ILs) are being increasingly studied in many different areas of physical chemistry because of the attractive properties of ILs. In particular, waterless microemulsions where the IL represents the polar phase can be of interest for those applications that demand the nanosegregation of polar substances, but in which the absence of water is a strict requirement. In this work, we prepared a reverse, nonaqueous microemulsion based on the low-viscosity room-temperature IL, 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide , the surfactant Brij 30, and n-nonane. The systems were characterized by dynamic light scattering and small-angle X-ray scattering; the IL/oil microemulsion was further employed as a templating system for the synthesis of gold nanoparticles from hydrogen tetrachloroaurate(III), HAuCl4, by UV-photoreduction technique.
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