Multi-principal element transition metal dichalcogenides via reactive fusion of 3D-heterostructures
Ihor Z Hlova1, Oleksandr Dolotko, Brett W Boote
1Ames Laboratory of U.S. Department of Energy, Iowa State University, Ames, IA 50011-2416, USA. vbalema@ameslab.gov.
Abstract:
Transition metal dichalcogenides combining multiple principal elements in their structures are synthesized via mechanochemical exfoliation and spontaneous reassembly of binary precursors into 3D-heterostructures that are converted into single-phase layered materials by high-temperature reactive fusion. Physical and chemical events enabling these transformations are summarized in the form of a conceivable reaction mechanism.
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