Self-supported nickel-cobalt nanowires as highly efficient and stable electrocatalysts for overall water splitting

The development and design of highly active and stable electrocatalysts based on cheap and Earth-abundant materials is critically important to enable water splitting as a desirable renewable energy source. Herein, we fulfill the significant electrochemical water splitting enhancement in both electrocatalytic activity and durability by constructing self-supported nickel-cobalt nanowire catalysts with abundant oxygen vacancies. Specifically, the rich oxygen vacancies can largely promote the oxygen evolution reaction (OER) activity of optimal Ni₁Co₁O₂ NWs with a relatively low overpotential of 248 mV to drive a current density of 10 mA cm^-2. More significantly, after the phosphorization of Ni₁Co₁O₂ NWs, the resultant Ni₁Co₁P NWs can also display excellent electrocatalytic hydrogen evolution reaction (HER) performances with an overpotential of only 101 mV to achieve a current density of 10 mA cm^-2. Furthermore, benefiting from the unique 1D nanowire structure, the synergistic effect, and the optimal Gibbs free energy for hydrogen evolution evolved from the phosphorization, the Ni₁Co₁O₂ NWs//Ni₁Co₁P NWs couple is thus highly active and stable for overall water electrolysis with a low voltage of 1.58 V at 10 mA cm^-2, showing extraordinary promise for practical overall water splitting electrolysis.