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Diverse reactivity of a boraguanidinato germylene toward organic pseudohalides
Jiří Böserle1, Grigory Zhigulin, Sergey Ketkov
1Department of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, Studentská 573, CZ-532 10, Pardubice, Czech Republic. libor.dostal@upce.cz.
Abstract:
The reactions of the boraquanidinato germylene (i-Pr)2NB(NDmp)2Ge (1) (Dmp = 2,6-Me2C6H3) with RN3 and RNCS produced rare examples of Ge2N and Ge3S rings, while the treatment of 1 with RNCO led to an insertion into the N-Ge bond leading to a novel type of germylene stabilized within a six membered ring, i.e. [N(R)C(O)N(Dmp)B(N(i-Pr)2)N(Dmp)]Ge (R = t-Bu or Ad).
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