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Updated: Feb 4, 2026

Synthesis and Characterization of Functionalized Metal-organic Frameworks
Published on: September 5, 2014
Trianglamine-Based Supramolecular Organic Framework with Permanent Intrinsic Porosity and Tunable Selectivity
Arnaud Chaix1, Georges Mouchaham2, Aleksander Shkurenko2
1Smart Hybrid Materials (SHMs) Laboratory, Advanced Membranes and Porous Materials Center, Division of Physical Sciences and Engineering , King Abdullah University of Science and Technology (KAUST) , Thuwal 23955-6900 , Saudi Arabia.
Abstract:
Here we introduce for the first time a metal-free trianglamine-based supramolecular organic framework, T-SOF-1, with permanent intrinsic porosity and high affinity to CO2. The capability of tuning the pore aperture dimensions is also demonstrated by molecular guest encapsulation to afford excellent CO2/CH4 separation for natural gas upgrading.
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