Related Experiment Video
Updated: Feb 4, 2026

Synthesis of Cyclic Polymers and Characterization of Their Diffusive Motion in the Melt State at the Single Molecule Level
Published on: September 26, 2016
Synthesis of Isomeric Perylenodithiophene Diimides
Cheng Zeng1,2, Dong Meng1, Wei Jiang1
1CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry , Chinese Academy of Sciences , Beijing 100190 , P. R. China.
Abstract:
Two isoelectronic dithiophene-fused perylene diimides (PDTI-1 and PDTI-2) were synthesized via a " bay-derivatization toward lateral extension" strategy. Single-crystal analysis unambiguously confirmed their unique structures and packing arrangements. The new PDTI system manifested significantly red-shifted absorptions with intense bands at 500-700 nm. Further dimerization indicated the potential of these dithiophene-fused PDIs as new building blocks for the construction of versatile rylene dyes in optoelectronic devices.
Related Concept Videos
Structural Isomerism
Isomers are different chemical species that have the same chemical formula. Structural isomerism of coordination compounds can be divided into two subcategories, the linkage isomers and coordination-sphere isomers.
Linkage isomers occur when the coordination compound contains a ligand that can bind to the transition metal center through two different atoms. For example, the CN− ligand can bind through the carbon atom or through the nitrogen atom. Similarly, SCN− can...
Isomerism
Isomerism in Alkenes
An isomer is called cis-2-butene when the methyl groups are on the same side of the double bond, and the other stereoisomer, in which methyl groups are on the opposite side of the double bond, is called trans-2-butene. The cis and trans stereoisomers are not...
Transfer RNA Synthesis
Each of these chemical modifications is carried by a specific enzyme, post-transcription. All of these enzymes have unique base and site-specificity. Methylation, the most common chemical modification, is carried by at least nine different enzymes, with...
Disubstituted Cyclohexanes: cis-trans Isomerism
In cyclohexane, the substituents can occupy different positions generating distinct isomers....
Ribosomal RNA Synthesis
Ribosome biogenesis begins with the synthesis of 5S and 45S pre-rRNAs by distinct RNA polymerases. The primary transcripts are extensively processed and modified before they are bound and folded by ribosomal proteins and assembly factors,...

