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Published on: March 31, 2018
Applying MOF+ technique for in situ preparation of a hybrid material for hydrogenation reaction
Yuan Tao1, Hui Qiong Wu, Jian Qiang Li
1State Key Laboratory for Nuclear Resources and Environment, and School of Biology, Chemistry, and Material Science, East China University of Technology, Nanchang, Jiangxi 344000, China. ecitluofeng@163.com.
Abstract:
In this study, we present the first case of applying the MOF+ technique for in situ preparation of a hybrid material, namely, Zn-MOF-74@ (Pd@Fe2O3). This as-synthesized material can well maintain both the integrity of the framework and porosity. Notably, Zn-MOF-74@(Pd@Fe2O3) exhibits outstanding catalytic performance in the hydrogenation reaction of alkene and semihydrogenation reaction of phenylacetylene, thus providing a new guideline for the design of MOF-based hybrid materials for catalytic purpose.
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