Removal of acetylsalicylate and methyl-theobromine from aqueous environment using nano-photocatalyst WO₃-TiO₂ @g-C₃N₄ composite

Highly efficient, visible light-driven and a novel ternary hybrid photocatalyst WO₃-TiO₂-g-C₃N₄ with robust stabilities and versatile properties has been synthesized through facile hydrothermal method. This study considers the photo-degradation of aspirin (acetylsalicylate) and caffeine (methyl-theobromine) via photocatalysts (WO₃, WO₃/TiO_2, and WO₃/TiO₂/g-C₃N₄ (WTCN) composite) under visible-light irradiation. The SEM and TEM images show the formation of WO₃ nanoparticles with orthorhombic structure and average particle size of 65 nm. The photocatalyst WTCN composite possesses higher-catalytic activity when compared to that of WO₃ and WO₃/TiO₂ for degradation of aspirin and caffeine. The incorporation of g-C₃N₄ in WO₃/TiO₂ composite exhibited significant influence on the photocatalytic performance for both pollutants. Excellent photocatalytic performance of WTCN composite was observed owing to hydroxyl radical (OH) and superoxide radical (O₂^-) as main active species. The enhanced photocatalytic activity of WTCN composite can be attributed to following three reasons: (1) extended visible-light absorption; (2) extended surface area; (3) efficient charge-separation due to synergistic effects between g- and WO₃/TiO₂ composite. The removal efficiency of aspirin and caffeine (Methyl theobromine) could be achieved as much as 98% and 97% for acetylsalicylate and methyl-theobromine using WTCN composite material, respectively. This study could provide new insights into the synthesis of novel WO₃-based materials for environmental and energy applications.