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Updated: Feb 4, 2026

Author Spotlight: Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers
Published on: May 12, 2023
Catalytic hydrogenation of carboxylic acids using low-valent and high-valent metal complexes
1Graduate School of Science, Nagoya University, Chikusa, Nagoya, 464-8602, Japan. saito.susumu@f.mbox.nagoya-u.ac.jp.
Abstract:
Carboxylic acids are ubiquitous in bio-renewable and petrochemical sources of carbon. The hydrogenation of carboxylic acids to alcohols generates water as the only by-product, and thus represents a sustainable method for the production of these alternative energy carriers/platform chemicals on a large scale. Herein, we offer a brief account of the development of this new concept and molecular insights into cationic mononuclear low- and high-valent transition-metal complexes for the hydrogenation of carboxylic acids.
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