Highly Tunable Multicolor Water-Jet Rewritable Paper Based on Simple New-Type Dual-Addressable Oxazolidines

Rewritable paper based on switchable molecules has attracted great attention in both academic research and marketplace. However, most available switchable dyes have single switchable color state only, which cannot meet the long-awaited multicolor reversible displays. Herein, through simple introduction of phenolic hydroxyl group, we develop a series of new oxazolidines with one switch unit, which could reversibly display two different as well as their mix-gradient colors by treating with water and mild acid, respectively, both in solution and solid substrate. The structures and mechanism for the formation of two colors had been studied in detail via UV-vis/NMR spectroscopy, skillfully designing contrast molecules, and kinetics experiments. This multiple switchable colors of the dyes have been further applied to construct a rewritable paper for ink-free printing with multi/gradient-color display.