Sedimentation Velocity and Potential in Dilute Suspensions of Charged Porous Shells

The sedimentation of a charged spherical porous shell with arbitrary inner and outer radii, which can model a permeable microcapsule or vesicle, in a general electrolyte solution is analytically examined. The relaxation effect in the electric double layers of arbitrary thickness around the porous shell is considered. The differential equations governing the electric potential profile, ionic electrochemical potential energy (or concentration) distributions, and fluid velocity field are linearized by taking the system to be only slightly distorted from equilibrium. These linearized equations are solved using a perturbation method with the density of the fixed charge of the porous shell as the small perturbation parameter. Closed-form formulas for the sedimentation velocity of a porous shell and sedimentation potential in a suspension of porous shells are obtained from a force balance and a zero current requirement, respectively. Both the charge-induced sedimentation velocity retardation and sedimentation potential are monotonic increasing functions of the relative shell thickness, and these increases are substantial if the shell is thin. The sedimentation velocity and potential are complex functions of the electrokinetic radius and normalized flow penetration length of the porous shell. In the limit of the porous shells with zero inner radius, our formulas for the sedimentation velocity and potential reduce to the results obtained for the intact porous spheres.