Coinage metal complexes of NHC-stabilized silyliumylidene ions
Philipp Frisch1, Shigeyoshi Inoue
1Department of Chemistry, WACKER-Institute of Silicon Chemistry and Catalysis Research Center, Technische Universität München, Lichtenbergstraße 4, 85748 Garching bei München, Germany. s.inoue@tum.de.
Abstract:
The first silyliumylidene ion coinage metal complexes are reported. Treatment of N-heterocyclic carbene (NHC) stabilized silyliumylidene ions (R = m-Ter, Tipp) with transition metal precursors (CuCl, AgOTf, (Me2S)AuCl) yields the first silyliumylidene coinage metal (M = Cu, Ag, Au) complexes, which have been fully characterized including X-ray diffraction analyses.
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