Synthetic strategies and application of gold-based nanocatalysts for nitroaromatics reduction

With the increasing requirement of efficient organic transformations on the basic concept of Green Sustainable Chemistry, the development of highly efficient catalytic reaction system is greatly desired. In this case, gold (Au)-based nanocatalysts are promising candidates for catalytic reaction, especially for the reduction of nitroaromatics. They have attracted wide attention and well developed in the application of nitroaromatics reduction because of the unique properties compared with that of other conventional metal-based catalysts. With this respect, this review proposes recent trends in the application of Au nanocatalysts for efficient reduction process of nitroaromatics. Some typical approaches are compared and discussed to guide the synthesis of highly efficient Au nanocatalysts. The mechanism on the use of H₂ and NaBH₄ solution as the source of hydrogen is compared, and that proposed under light irradiation is discussed. The high and unique catalytic activity of some carriers, such as oxides and carbons-based materials, based on different sizes, structures, and shapes of supported Au nanocatalysts for nitroaromatics reduction are described. The catalytic performance of Au combining with other metal nanoparticles by alloy or doping, like multi-metal nanoparticles system, is further discussed. Finally, a short discussion is introduced to compare the catalysis with other metallic nanocatalysts.