Giant Microgels with CO₂-Induced On-Off, Selective, and Recyclable Adsorption for Anionic Dyes

Adsorbents that are capable of controllable pollutants adsorption and release without secondary pollution are attractive in water treatment. Here, we propose eco-friendly CO₂ as a trigger to switch the charge states and collapse-expansion transition of giant microgels consisting of hydrophilic acrylamide and hydrophobic 2-(diethylamino)ethyl methacrylate and demonstrated the on-off, selective, and recyclable adsorption of anionic dyes on microgels under CO₂ stimulation. Apart from easy-handling separation from the water by a simple filtration process, the maximum adsorption capacity is as high as 821 mg g^-1, and the adsorption isotherms and kinetics obeyed Langmuir isotherm and the pseudo-second-order kinetics models, respectively. The anionic dye can also be separated from the mixture solution using CO₂-treated microgels. Moreover, a wastewater treatment prototype with microgel-packed column was fabricated. Under continuous flow condition, the dye was removed and recovered by alternative bubbling CO₂ and flushing with aqueous alkali (pH 12). Thus, this type of microgels with CO₂-induced protonation-deprotonation transition can serve as a cost-effective, environmentally friendly, and efficient adsorbent for water purification applications.