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Updated: Feb 3, 2026

Adsorption Device Based on a Langatate Crystal Microbalance for High Temperature High Pressure Gas Adsorption in Zeolite H-ZSM-5
Published on: August 25, 2016
Room temperature methoxylation in zeolite H-ZSM-5: an operando DRIFTS/mass spectrometric study
Santhosh K Matam1, Russell F Howe, Adam Thetford
1Department of Chemistry, University College London, London, WC1E 6BT, UK.
Abstract:
At high loading, methanol reacts under ambient conditions with acidic hydroxyls of H-ZSM-5 to methoxylate framework oxygen; while a significant proportion remains hydrogen bonded to the framework with a protonated geometry. The findings not only explain the data which have been published so far, but also pave a way forward for potential unravelling of the initial reaction steps in the relevant chemical processes.
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