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A new "bicycle helmet"-like copper(ii),sodiumphenylsilsesquioxane. Synthesis, structure and catalytic activity
Alena N Kulakova1, Alexey N Bilyachenko, Alexander A Korlyukov
1Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov Str., 28, 119991 Moscow, Russia. bilyachenko@ineos.ac.ru.
Dalton Transactions (Cambridge, England : 2003)
|November 1, 2018
Abstract:
A new "bicycle helmet"-like copper(ii),sodiumphenylsilsesquioxane Ph12Si12O12(OH)(O-)11Cu5Na(bipy)3(H2O) exhibited high catalytic efficiency in two homogeneous reactions: (i) functionalization of C-H compounds; (ii) formation of benzamides from alcohols.