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Construction and Magnetic Study of a Trigonal-Prismatic Cobalt(II) Single-Ion Magnet
Binling Yao1, Yi-Fei Deng1, Tianran Li1
1Department of Chemistry , Southern University of Science and Technology (SUSTech) , Shenzhen 518055 , China.
Abstract:
A new tripodal hexadentate ligand of tris[6-(1 H-pyrazol-1-yl)pyridin-2-yl]methanol (tppm) was synthesized and explored for constructing the trigonal-prismatic cobalt(II) complex [Co(tppm)][ClO4]2·2CH3CN·H2O (1). Magnetic study showed that 1 exhibited large uniaxial magnetic anisotropy with a zero-field-splitting parameter of -80.7 cm-1 and typical single-molecule-magnet behavior.
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