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Scale-up Chemical Synthesis of Thermally-activated Delayed Fluorescence Emitters Based on the Dibenzothiophene-S,S-Dioxide Core
Published on: October 24, 2017
Highly efficient single-stack hybrid cool white OLED utilizing blue thermally activated delayed fluorescent and
Gyeong Woo Kim1, Hyeong Woo Bae1, Raju Lampande1
1Department of Information Display, Kyung Hee University, Dongdaemoon-gu, Seoul, 130-701, Republic of Korea.
This study presents highly efficient single-stack hybrid cool white organic light-emitting diodes (OLEDs) using blue thermally activated delayed fluorescence (TADF) and yellow phosphorescent emitters. Optimized device structure and recombination zone control achieve superior cool white emission for displays.
Area of Science:
- Materials Science
- Organic Electronics
- Solid State Physics
Background:
- Organic light-emitting diodes (OLEDs) are crucial for display technologies.
- Achieving efficient and stable cool white emission in single-stack OLEDs remains a challenge.
- Hybrid approaches combining different emitter types offer potential for improved performance.
Purpose of the Study:
- To design and construct highly efficient single-stack hybrid cool white OLEDs.
- To optimize out-coupling efficiency for both blue and yellow emissions.
- To control exciton formation for desired cool white emission characteristics.
Main Methods:
- Utilized blue thermally activated delayed fluorescent (TADF) and yellow phosphorescent emitters.
- Engineered blue-yellow-blue multiple emitting layers (EMLs).
- Tuned ITO and total device thickness to satisfy antinode conditions for emissions.
- Manipulated recombination zone via host medium conductivity variation.
Main Results:
- Achieved a maximum external quantum efficiency of 23.1% for cool white emission.
- Obtained CIE color coordinates of (0.324, 0.337), indicating high-quality white light.
- Demonstrated effective control over exciton formation ratio and recombination zone.
Conclusions:
- The developed single-stack hybrid OLED architecture is highly viable for advanced display applications.
- Optimizing device thickness and charge conductivity is key to efficient hybrid white OLEDs.
- This approach offers a promising pathway for high-performance display technology.
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