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Obtaining fermentable sugars and bioproducts from rice husks by subcritical water hydrolysis in a semi-continuous
Ederson R Abaide1, Gustavo Ugalde2, Marco Di Luccio3
1Department of Chemical Engineering, Federal University of Santa Maria, 1000, Roraima Avenue, Santa Maria, RS 97105-900, Brazil; Laboratory of Agroindustrial Processes Engineering (LAPE), Federal University of Santa Maria (UFSM), 1040, Sete de Setembro St, Center DC, Cachoeira do Sul - RS 96508-010, Brazil.
Abstract:
This work aimed at producing fermentable sugars and bioproducts from rice husks by subcritical water hydrolysis at 25 MPa in a semi-continuous mode. The influences of temperature (180 °C; 220 °C; 260 °C) and liquid/solid ratio (7.5 g water/g husks; 15 g water/g husks) on reducing sugar yield (YRS), efficiency (E), kinetic profiles (0-15 min), composition of sugars, inhibitors and organic acids, and physicochemical characteristics of the remaining solid material were evaluated and discussed in the work. The highest YRS (18.0 ± 2.9 g/100 g husks) and E (39.5 ± 1.7 g sugars/100 g carbohydrates) were obtained at 220 °C and 7.5 gwater/g husks. In such condition, the hydrolyzed solutions presented cellobiose (18.0 g/L), xylose 17.7 g/L), arabinose (3.6 g/L), glucose (1.5 g/L), and levulinic acid (0.7 g/L). The fermentable sugars and bioproducts can be applied in several industrial fields, especially for the production of bioethanol and other higher value-added chemical compounds.
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