Simultaneous removal of methylene blue and Pb²⁺ from aqueous solution by adsorption on facile modified lignosulfonate

In this paper, simultaneous removal of methylene blue (MB) and Pb²⁺ from the binary component system by an easily prepared cross-linked lignosulfonate bio-adsorbent (CLLS) was described. CLLS was characterized by FTIR, SEM/EDS and TGA. The influences of pH, temperature, contact time and initial MB and Pb²⁺ concentrations on the adsorption performance were investigated. The results demonstrated a good ability of CLLS to remove MB and Pb²⁺ simultaneously. Using of 1.0 g L^-1 loading, removal efficiency of MB and Pb²⁺ reached 98.0% and 97.8%, respectively, in the MB (100 mg.L^-1)-Pb²⁺ (50 mg.L^-1) system. Moreover, the adsorption isotherms and adsorption kinetics indicated that the results were fitting well with the Langmuir and pseudo-second-order model, respectively, for both MB and Pb²⁺. Based on the Langmuir model, the maximum adsorption capacity of MB and Pb²⁺ reached 132.6 and 64.9 mg g^-1, respectively, in the MB-Pb²⁺ system, which was much lower than that in the single component system (358.4 mg g^-1 100.9 mg g^-1 for MB and Pb²⁺, respectively). Hence, simultaneous adsorption of MB and Pb²⁺ onto CLLS was an antagonistic adsorption. In addition, an apart-sequential adsorption method was used to study the action of adsorption sites on CLLS for MB and/or Pb²⁺ with the help of an efficient self-made apparatus. Rudimental results showed that there would be three different kinds of adsorption sites on CLLS: MB-site, Pb²⁺-site and MB/Pb²⁺- shared sites. Furthermore, in the MB (100 mg.L^-1)-Pb²⁺(50.0 mg.L^-1) system, the simultaneous removal efficiency of MB and Pb²⁺ still maintained 91.8% and 85.0%, respectively, after 6 cycles.