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Secondary-Transferring Graphene Electrode for Stable FOLED.

Yunjie Teng1, Shoufeng Tong2, Min Zhang3

  • 1College of Opto-Electronic Engineering, Changchun University of Science and Technology, Changchun, 130012, People's Republic of China.

Nanoscale Research Letters
|November 8, 2018
PubMed
Summary

Sharp wrinkles on graphene films, caused by copper foil grain boundaries, were addressed. A secondary-transferring process smoothed graphene surfaces, enhancing its use in stable flexible organic light-emitting devices (FOLEDs).

Keywords:
Flexible organic light emitting deviceGrapheneSecondary-transferringSharp winkles

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Area of Science:

  • Materials Science
  • Nanotechnology
  • Surface Science

Background:

  • Graphene films prepared on copper foil often exhibit sharp wrinkles.
  • These wrinkles originate from the duplication of copper grain boundary cracks during graphene synthesis.
  • Surface morphology defects negatively impact graphene's electronic and device applications.

Purpose of the Study:

  • To explore the formation mechanism of sharp wrinkles on graphene films.
  • To develop a novel method for smoothing wrinkled graphene surfaces.
  • To demonstrate the improved performance of graphene in electronic devices after surface modification.

Main Methods:

  • Investigated wrinkle formation by analyzing graphene grown on copper foil.
  • Developed a secondary-transferring process to modify graphene surface morphology from "Peak" to "Valley" form.
  • Evaluated surface morphology and photo-electric properties before and after the secondary-transferring process.

Main Results:

  • The secondary-transferring process effectively smoothed graphene surface wrinkles with minimal damage.
  • Fabricated flexible organic light-emitting devices (FOLEDs) using modified single-layer graphene (SLG).
  • Achieved high performance in FOLEDs, with maximum luminance of 35000 cd/m² and current efficiency of 16.19 cd/A.

Conclusions:

  • The proposed secondary-transferring method successfully mitigates graphene wrinkles caused by substrate defects.
  • This technique significantly enhances the stability and performance of graphene-based devices like FOLEDs.
  • The method is suitable for scalable, high-quality graphene production via roll-to-roll manufacturing.