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A Dewetting Model for Double-Emulsion Droplets.

Zhanxiao Kang1,2, Pingan Zhu3,4, Tiantian Kong5,6

  • 1Department of Mechanical Engineering, The University of Hong Kong, Hong Kong, China. zxkang@connect.hku.hk.

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|November 9, 2018
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Summary
This summary is machine-generated.

The study reveals how double-emulsion droplet evolution is driven by interfacial tensions and viscosity. Equilibrium configurations depend on interfacial tension ratios, influencing dewetting time in microparticle applications.

Keywords:
dewetting forcedewetting timedouble emulsionequilibrium configuration

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Area of Science:

  • Fluid dynamics
  • Materials science
  • Physical chemistry

Background:

  • Double-emulsion droplets are crucial for microdroplet and microparticle applications.
  • Understanding droplet evolution, including dewetting, is key to controlling microparticle formation.

Purpose of the Study:

  • To investigate the driving forces behind the dewetting process of double-emulsion droplets.
  • To determine the equilibrium configuration and predict the dewetting time of these droplets.

Main Methods:

  • Energy analysis was employed to understand droplet equilibrium.
  • A dewetting boundary concept was introduced to calculate dewetting time.
  • The study balanced driving forces (interfacial tensions) against viscous forces.

Main Results:

  • Equilibrium configuration depends on a dimensionless interfacial tension, influenced by three interfacial tensions.
  • Increased outer phase volume leads to a larger engulfed inner phase.
  • Dewetting time increases with outer phase viscosity and the volume ratio of outer to inner phases.

Conclusions:

  • The study provides insights into the physical mechanisms governing double-emulsion droplet evolution.
  • Predictive models for dewetting time can be developed based on interfacial properties and phase volumes.
  • Findings are applicable to the controlled fabrication of microparticles and microdroplets.