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Range00:59

Range

14.2K
The range is one of the measures of variation. It can be defined as the difference between a dataset's highest and lowest values. For example, in the study of seven 16-ounce soda cans, the filled volume of soda was measured, thus producing the following amount (in ounces) of soda:
15.9; 16.1; 15.2; 14.8; 15.8; 15.9; 16.0; 15.5
Measurements of the amount of soda in a 16-ounce can vary since different subjects record these measurements or since the exact amount - 16 ounces of liquid, was not...
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Social Exchange Theory02:06

Social Exchange Theory

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We have discussed why we form relationships, what attracts us to others, and different types of love. But what determines whether we are satisfied with and stay in a relationship? One theory that provides an explanation is social exchange theory. According to social exchange theory, we act as naïve economists in keeping a tally of the ratio of costs and benefits of forming and maintaining a relationship with others (Rusbult & Van Lange, 2003).
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Social Exchange Theory01:26

Social Exchange Theory

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As formulated by John Thibaut and Harold Kelley, Social Exchange Theory explains human relationships as economic-like exchanges that maximize rewards and minimize costs. This theory suggests that individuals engage in relationships to gain benefits and reduce burdens, similar to economic transactions. It has been widely applied to various types of relationships, including romantic, professional, and social interactions.Rewards and Costs in RelationshipsRelationship rewards include emotional...
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¹H NMR: Long-Range Coupling01:27

¹H NMR: Long-Range Coupling

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The coupling interactions of nuclei across four or more bonds are usually weak, with J values less than 1 Hz. While these are usually not observed in spectra, the presence of multiple bonds along the coupling pathway can result in observable long-range coupling.
In alkenes, spin information is communicated via σ–π overlap, as seen in allylic (four-bond) and homoallylic (five-bond) couplings. These coupling interactions are stronger when the σ bond is parallel to the alkene...
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Density00:56

Density

19.9K
Density is an important characteristic of substances, crucial in determining whether an object sinks or floats in a fluid. Its SI unit is kg/m3, and its cgs unit is g/cm3. The density of an object helps in identifying its composition, and also reveals information about the phase of the matter and its substructure. The densities of liquids and solids are roughly comparable, consistent with the fact that their atoms are in close contact. However, gases have much lower densities than liquids and...
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Applications of Integration to Probability Density Functions01:27

Applications of Integration to Probability Density Functions

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Continuous probability distributions are used to model random variables that can take on any real value within a specified range. These variables do not take on isolated or countable values but rather exist on a continuum. For example, the height of an individual can be measured with increasing precision—such as 163.5 or 165.25 centimeters—demonstrating that height is a continuous random variable.The behavior of such variables is described using a probability density function (PDF),...
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Related Experiment Video

Updated: Feb 2, 2026

Separating Bacteria by Capsule Amount Using a Discontinuous Density Gradient
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Four-component relativistic range-separated density-functional theory: Short-range exchange local-density

Julien Paquier1, Julien Toulouse1

  • 1Laboratoire de Chimie Théorique (LCT), Sorbonne Université and CNRS, F-75005 Paris, France.

The Journal of Chemical Physics
|November 10, 2018
PubMed
Summary
This summary is machine-generated.

We extended range-separated density-functional theory to a four-component relativistic framework. This approach accurately models short-range electron interactions, crucial for high-density systems.

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Area of Science:

  • Quantum Chemistry
  • Computational Physics
  • Theoretical Chemistry

Background:

  • Density-functional theory (DFT) is a powerful quantum mechanical modeling method.
  • Relativistic effects become significant for heavy elements and high electron densities.
  • Accurate modeling of electron-electron interactions is essential for chemical accuracy.

Purpose of the Study:

  • To extend range-separated density-functional theory to a four-component relativistic framework.
  • To develop a short-range exchange approximation suitable for relativistic calculations.
  • To investigate the impact of relativistic effects on short-range exchange interactions.

Main Methods:

  • Utilized a four-component relativistic framework with a Dirac-Coulomb-Breit Hamiltonian in the no-pair approximation.
  • Combined a wave-function method for long-range electron-electron interactions with density functional theory for short-range interactions.
  • Constructed a short-range exchange local-density approximation based on a relativistic homogeneous electron gas.

Main Results:

  • Developed a novel relativistic short-range exchange local-density approximation.
  • Provided systematically improvable Padé approximants for relativistic exchange energies.
  • Demonstrated the significant impact of relativity on short-range exchange effects at high densities.

Conclusions:

  • The developed formalism accurately captures relativistic effects in short-range exchange interactions.
  • This method is crucial for accurate electronic structure calculations of heavy elements.
  • The findings pave the way for more precise relativistic quantum chemical calculations.