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Lignin oxidation with an organic peroxide and subsequent aromatic ring opening

Mónica R C Fernandes1, Xiaoming Huang2, Hendrikus C L Abbenhuis3

  • 1Schuit Institute of Catalysis, Laboratory of Inorganic Materials and Catalysis, Eindhoven University of Technology, PO Box 513, 5600 MB Eindhoven, the Netherlands; Hybrid Catalysies B.V., PO Box 513, 5600 MB Eindhoven, the Netherlands.

International Journal of Biological Macromolecules
|November 21, 2018
PubMed
Summary

Titanium-initiated oxidation of organosolv lignin using tert-butylhydroperoxide causes structural changes. Grafted titanium catalyzes aromatic ring opening, making lignin more susceptible to depolymerization into valuable monomers.

Keywords:
Aromatic ring openingBiomassLigninOxidation

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