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Porous magnetic resin-g-chitosan beads for adsorptive removal of phenolic compounds
Jalil Heydaripour1, Mustafa Gazi1, Akeem Adeyemi Oladipo2
1Polymeric Materials Research Laboratory, Department of Chemistry, Faculty of Arts & Science, Eastern Mediterranean University, Famagusta, TR North Cyprus, via Mersin 10, Turkey.
Abstract:
In this study, porous magnetic resin grafted chitosan (R-g-Ch) beads were prepared for removal of 4-chlorophenol and phenol from aqueous solutions. The R-g-Ch beads were characterized by vibrating sample magnetometer, Fourier-transform infrared spectroscopy, scanning electron microscopy and thermogravimetry methods. The removal of the phenolic compounds was optimized by varying the experimental conditions. Results herein are well fitted to the pseudo-second order kinetic and Langmuir isotherm. The maximum adsorption capacity of phenol and 4-chlorophenol were found to be 188.6 and 99 mg/g, respectively. The thermodynamic studies suggested that the adsorption process was exothermic, irreversible and feasible within the range of 298-318 K.
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