Determination of adulterated gasoline using fluorescence emission-excitation matrices and multivariate calibration

Methanol gasoline, known as a new energy, has a certain degree of damage to automobile. The aim of this work was to identify and quantify the methanol in methanol gasoline using three-dimensional fluorescence spectroscopy technique combined with second order chemometric methods. Parallel factor analysis (PARAFAC) and self-weighted alternating trilinear decomposition (SWATLD) methods were used to analyse artificial samples. However, the obtained results by PARAFAC were not satisfactory. On the other hand, excellent prediction results were obtained when SWATLD model was applied, with recovery rate between 98.7 and 102.8%, and between 97.4 and 101.9% for two and three factor respectively. In order to verify the accuracy of the method, four real samples were predicted using SWATLD model with RMSEP between 0.1 μg/mL and 0.23 μg/mL.