An experimental and kinetic study of thermal decomposition of phenanthrene

Polycyclic aromatic hydrocarbons (PAHs) have enormous potential hazards. It is necessary for China to propose more internationally stricter standards for PAHs, in order to improve the country's pollutant prevention and control policy system, and ultimately, provide institutional guarantees for implementing PAH emissions prevention and control. In this study, phenanthrene, a typical PAHs generated during municipal solid waste (MSW) to energy system, was applied as a model compound to study the thermal degradation mechanism during the combustion process. Combustion kinetics for the three major gaseous products, including hydrogen, methane, and carbon dioxide, were determined. Experimental results indicated that hydrogen was promoted compared to methane and carbon dioxide during the combustion of phenanthrene, especially in high oxygen concentrations. The apparent activation energy (E_a) of 8.299-11.51, 13.10-23.07, and 9.368-15.29 kJ/mol, pre-exponential factor (A) of 0.219-1.579, 5.034-10.12, and 6.553-15.51 s^-1, and the reaction order (n) of 1.160-1.234, 1.059-1.305, and 1.636-1.774 were obtained for hydrogen, methane, and carbon dioxide, respectively. Research on combustion behavior of phenanthrene and reaction kinetics provides the theoretical basis for the high-temperature removal of PAHs as byproducts during the combustion of MSW in oxygen-rich atmosphere.