Ultrahigh Selective Colorimetric Quantification of Chromium(VI) Ions Based on Gold Amalgam Catalyst...

Hexavalent chromium ion (Cr⁶⁺) is one of the most toxic substances for plants, for animals, and is a confirmed human respiratory carcinogen. However, so far, there are few independent and efficient colorimetric methods for detection of Cr⁶⁺. Here, we introduce a convenient, label-free, catalysis-based, and efficient strategy for quantification of Cr⁶⁺ by using a colorimetric sensing probe 3,3',5,5'-tetramethylbenzidine (TMB). In the presence of a trace amount of gold amalgam nanocomposites (Au@Hg) and Cr⁶⁺, TMB can be oxidized to oxTMB and the color changed to an intense blue that was observed by naked-eye and absorption spectroscopic method. In addition, the colorimetric method shows the high selectivity against 34 other interfering substances, and it can be performed at room temperature, in water, and requires only ∼5 min. Thus, the catalysis-based colorimetric assay for accurate and ultrahigh selective identification of Cr⁶⁺ will find widespread use in the world.