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Updated: Feb 2, 2026

Preparation of Carbon Nanosheets at Room Temperature
Published on: March 8, 2016
Ring-opening polymerization of trimethylene carbonate to poly(trimethylene carbonate) diol over a heterogeneous
Masazumi Tamura1, Keitaro Matsuda, Yoshinao Nakagawa
1Graduate School of Engineering, Tohoku University, Aoba 6-6-07, Aramaki, Aoba-ku, Sendai, 980-8579, Japan. mtamura@erec.che.tohoku.ac.jp tomi@erec.che.tohoku.ac.jp.
Abstract:
CeO2 calcined at 1273 K showed higher activity per surface area than other metal oxides in the ring-opening polymerization of trimethylene carbonate under neat conditions without any additives, providing metal-free and additive-free poly(trimethylene carbonate) diols with no ether bonds with high selectivity. It was demonstrated that CeO2 was a robust and reusable heterogeneous catalyst.
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