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Updated: Feb 1, 2026

Excitonic Hamiltonians for Calculating Optical Absorption Spectra and Optoelectronic Properties of Molecular Aggregates and Solids
Published on: May 27, 2020
Slave rotor approach to exciton condensation in a two-band system
Subhasree Pradhan1,2,3, A Taraphder1,4,5
1Department of Physics, Indian Institute of Technology Kharagpur, Kharagpur-721 302, West Bengal, India.
Abstract:
We have studied exciton formation and condensation in an extended Falicov-Kimball model, going beyond the weak coupling approach, employing a semi-analytical technique: the slave-rotor mean-field theory (SRMF). In this essentially strong coupling theory, charge and spin (or orbital/pseudospin) degrees are treated as independent degrees of freedom, coupled by a local constraint. Using a two-site-extension of SRMF, we capture the effective many body scale beyond conventional mean-field theory. While the formation of excitons is favoured by the interband hybridization [Formula: see text], it is strongly influenced by the on-site Coulomb interaction [Formula: see text]. Beyond a critical hybridization, there is condensation of excitons, leading to a transition from a metal to an excitonic insulator phase. Moreover, the behaviour of excitonic averages differs from the usual Hartree-Fock mean-field theory. Low-[Formula: see text] results show that excitonic order parameter (Δ) is continuous across the transition both for single as well as two-site approximation, changing to weakly first order one at intermediate [Formula: see text] for the later. The large-[Formula: see text] limit shows a continuous transition for two-site analysis but remains first order in the single-site approximation. The slave rotor theory gives a mixed state of excitons and metal in both the analyses. We have also checked the effect of intersite correlation and localized band hopping on the exciton condensation.
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