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Updated: Feb 1, 2026

Depolymerizable Olefinic Polymers Based on Fused-Ring Cyclooctene Monomers
Published on: December 16, 2022
Conjugated hybrid films based on a new polyoxotitanate monomer
Gang Liu1, Xing Yang, Antoine Bonnefont
1College of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou, 310014, China. czhang@zjut.edu.cn yaokanglv@zjut.edu.cn.
Abstract:
Electropolymerisation of the novel polyoxotitanate (POT) hexamer [Ti(μ3-O)(OiPr)(TA)]6 (TA = thiophene-3-acetate) with 3,4-ethylenedioxythiophene (EDOT) gives films of hybrid conjugated copolymer, Poly-(EDOT-POT)s, the morphologies of which are, uniquely, influenced by the electropolymerisation potential. Nanoporous Poly-(EDOT-POT)-1 is a fast-ion electrode material and has improved electrochromic properties and significantly higher capacitance than that of the parent poly(3,4-ethylenedioxythiophene) (PEDOT).
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