Multi-functional organic gelator derived from phenyllactic acid for phenol removal and oil recovery

Supramolecular gels, a fascinating class of soft materials, are of great interest for their wide applications. In this work, a series of organic gelators derived from phenyllactic acid were prepared, and their gelation properties were further investigated. It was found that the gelator 1e bearing a hydrazine moiety could congeal 17 kinds of common organic liquids (polar and non-polar) efficiently. Meanwhile, the morphological structures and dominant factors of the gel were examined by scanning electron microscope (SEM), transmission electron microscope (TEM), Fourier transform infrared spectroscopy (FT-IR), concentration and temperature-dependent ¹H NMR. Crucially, the gelator displayed outstanding performances in toxic phenol removal and spilled oil and petroleum products recovery. Moreover, it also displayed a satisfactory recyclability, which will greatly promote its application in practice. These impressive results will provide a novel avenue for the water treatment and the development of functional supramolecular gel materials.