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Updated: Feb 1, 2026

Controlling the Size, Shape and Stability of Supramolecular Polymers in Water
Published on: August 2, 2012
Water-Soluble Pillar[n]arene Mediated Supramolecular Self-Assembly: Multi-Dimensional Morphology Controlled by Host
Yamin Liu1, Kejia Shi1, Da Ma1
1Department of Chemistry, Fudan University, 220 Handan Road, Shanghai, 200433, China.
Abstract:
We report tunable supramolecular self-assemblies formed by water-soluble pillar[n]arenes (WPns, n=5-7) and bipyridinium-azobenzene guests. Nanoscale or microscale morphology of self-assemblies in water was controlled by the host size of WPn. Supramolecular self-assemblies could undergo morphology conversion under irradiation with UV light.
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