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Raman scattering from the bulk inactive out-of-plane mode in few-layer MoTe2
M Grzeszczyk1, K Gołasa1, M R Molas1,2
1Faculty of Physics, University of Warsaw, ul. Pasteura 5, 02-093 Warsaw, Poland.
Scientific Reports
|December 12, 2018
Summary
This study investigates Raman scattering in few-layer molybdenum ditelluride (MoTe2), revealing temperature-dependent double peaks in vibrational modes. This suggests resonant Raman scattering due to electronic band structure interactions.
Area of Science:
- Condensed Matter Physics
- Materials Science
- Spectroscopy
Background:
- Few-layer molybdenum ditelluride (MoTe2) exhibits unique vibrational properties.
- Out-of-plane vibrational modes are crucial for understanding MoTe2's lattice dynamics.
Purpose of the Study:
- To investigate high-frequency out-of-plane vibrational modes in few-layer MoTe2.
- To explore the temperature-dependent behavior and resonant characteristics of these modes.
Main Methods:
- Raman scattering spectroscopy was employed.
- Temperature-dependent measurements were conducted.
- Variable excitation laser energies (1.91 eV and 1.96 eV) were used.
Main Results:
- A double peak structure was observed in the Raman spectra of 4- and 5-layer MoTe2 near 291 cm-1.
- The lower and higher energy components of the doublet were attributed to inner and surface layer vibrations, respectively.
- A strong enhancement of the inner mode intensity was observed at low temperatures with specific laser excitations.
Conclusions:
- The observed double peak structure is linked to distinct vibrational contributions from inner and surface layers.
- The intensity enhancement suggests resonant Raman scattering.
- Resonance is proposed to occur with a singularity in the electronic density of states at the M point of the MoTe2 Brillouin zone.
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