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RAFT polymer cross-coupling with boronic acids
Hartwig Golf1, Riley O'Shea1, Carl Braybrook2
1School of Chemistry , Monash University , Clayton , Melbourne , VIC 3800 , Australia . Email: david.lupton@monash.edu ;
Abstract:
The ability to modify the thiocarbonylthio end-groups of RAFT polymers is important for applications where an inert or highly functionalised material is required. Here we report a copper promoted cross-coupling reaction between RAFT polymer end-groups and aryl boronic acids. This method gives high conversion to the modified polymers, and is compatible with a wide variety of functional molecules.
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