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Updated: Feb 1, 2026

In situ Photo-rheology Monitors Viscoelastic Changes in Photo-responsive Polymer Networks
Published on: June 20, 2025
Viscoelastic change of block copolymer ion gels in a photo-switchable azobenzene ionic liquid triggered by light
Caihong Wang1, Kei Hashimoto, Ryota Tamate
1Department of Chemical Machinery and Control Engineering, School of Chemical Engineering, Sichuan University, Sichuan 610065, China.
Abstract:
A photo-switchable ionic liquid solvent bearing an azobenzene moiety induced a viscoelastic change of block copolymer ion gels by light. ABA triblock copolymers having poly(phenethyl methacrylate) and poly(benzyl methacrylate) as A blocks exhibited opposite photoinduced rheological responses although they had only a tiny structural difference in the alkyl chain length.
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