Enhanced detoxification of p-bromophenol by novel Zr/Ag-TiO₂@rGO ternary composite: Degradation kinetics and...

The toxicity and persistence of the halogenated aromatics, particularly brominated phenolic compounds have drawn serious concerns to the environment, emphasizing the potential effects on human health and ecosystems balance. Advanced oxidation process (AOP) has received much attention as an alternative for the conventional wastewater treatment methods to treat water contaminated with toxic pollutants. This study investigated the degradation and detoxification of p-bromophenol (p-BP) by a novel Zr/Ag-TiO₂@rGO photocatalyst under visible light. Upon 3 h of visible light irradiation over Zr/Ag-TiO₂@rGO, more than 95% of p-BP (15 mg/L) degradation was achieved at a rate of 0.23 min^-1. The degradation products were identified by GC-MS and possible degradation pathway was proposed. The phytotoxicity evolution of the degraded products was assessed on Vigna radiata (V. radiata), in which seeds treated with pure p-BP showed less germination (40%) compared to degradation products (100%). Furthermore, the germination index (GI) of p-BP was found to be 11.1% before degradation while it increased to 80.5% after 3 h of degradation indicated that this photodegradation process achieved detoxification of p-BP. Thus, this study demonstrated that p-BP elimination and detoxification could be simply achieved with Zr/Ag-TiO₂@rGO nanocomposite under visible light irradiation, which provides new solution for wastewater treatment and water reuse in crop irrigation.