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1,8-Bis(dimethylamino)naphthyl-2-ketimines: Inside vs outside protonation

A S Antonov1,2, A F Pozharskii1, P M Tolstoy2

  • 1Department of Organic Chemistry, Southern Federal University, Zorge str. 7, 344090 Rostov-on-Don, Russian Federation.

Beilstein Journal of Organic Chemistry
|December 15, 2018
PubMed
Summary

Methoxy groups on ortho-arylketimines significantly boost nitrogen basicity, influencing protonation sites. This impacts hydrogen bonding and rotation dynamics in protonated naphthalene derivatives.

Keywords:
NMRhydrogen bondimineproton spongesuperbase

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