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Updated: Feb 1, 2026
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Synthesis and Characterization of Functionalized Metal-organic Frameworks
Published on: September 5, 2014
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Hollow Metal-Organic-Framework Micro/Nanostructures and their Derivatives: Emerging Multifunctional Materials
Di Liu1,2, Jiawei Wan3, Guangsheng Pang1
1Key Laboratory of Nanosystem and Hierarchical Fabrication, National Center for Nanoscience and Technology, Chinese Academy of Sciences, No. 11, Beiyitiao, Zhongguancun, Beijing, 100190, P. R. China.
Advanced Materials (Deerfield Beach, Fla.)
|December 15, 2018
Summary
Hollow metal-organic frameworks (MOFs) offer unique porous structures for enhanced catalysis and energy storage. This review summarizes their synthesis and applications, highlighting future research directions.
Area of Science:
- Materials Science
- Nanotechnology
- Chemistry
Background:
- Hollow metal-organic frameworks (MOFs) exhibit hierarchical porous structures.
- These structures offer accessible metal sites and 3D channels for efficient mass transport.
- Hollow MOFs show promise in catalysis, gas sensing, batteries, and supercapacitors.
Purpose of the Study:
- To comprehensively review synthetic strategies for hollow MOFs and their derivatives.
- To summarize the diverse practical applications of these materials.
- To discuss the relationship between structure and performance, and outline future prospects.
Main Methods:
- Literature review of synthetic methodologies for hollow MOFs.
- Analysis of structure-property relationships in various applications.
- Discussion of current challenges and future research opportunities.
Main Results:
- Hollow MOFs can be synthesized through various templating and template-free methods.
- Their unique architecture significantly enhances performance in catalysis, energy storage, and sensing.
- A comprehensive understanding of structure-performance links is crucial for further development.
Conclusions:
- Hollow MOFs and their derivatives are a rapidly developing field with significant potential.
- Further research into synthesis and application-specific design is warranted.
- This review provides a foundation for future studies in hollow MOF materials.
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