Integrating Catalysis of Methane Decomposition and Electrocatalytic Hydrogen Evolution with Ni/CeO₂ for Improved...

Ni/CeO₂ enables either methane decomposition or water electrolysis for pure hydrogen production. Ni/CeO₂ , prepared by a sol-gel method with only one heat treatment step, was used to catalyze methane decomposition for the generation of H₂ . The solid byproduct, Ni/CeO₂ /carbon nanotube (CNT), was further employed as an electrocatalyst in the hydrogen evolution reaction (HER) for H₂ production. The Ni/CeO₂ catalyst exhibits excellent activity for methane decomposition because CeO₂ prevents carbon encapsulation of Ni nanoparticles during the preparation process and forms a special metal-support interface with Ni. The derived CNTs act as antenna to improve conductivity and promote the dispersion of agglomerated Ni/CeO₂ . In addition, they provide H₂ diffusion paths and prevent Ni/CeO₂ from peeling off the HER electrode. Although long-term methane decomposition reduces the HER activity of Ni/CeO₂ /CNTs (owing to degradation of the delicate Ni/CeO₂ interface), the tunable nature of the synthesis makes this an attractive sustainable approach to synthesize future high-performance materials.