Related Experiment Video
Updated: Jan 31, 2026

Reductive Electropolymerization of a Vinyl-containing Poly-pyridyl Complex on Glassy Carbon and Fluorine-doped Tin Oxide Electrodes
Published on: January 30, 2015
Electrochemical CO2 reduction in water at carbon cloth electrodes functionalized with a fac-Mn(apbpy)(CO)3Br complex
Laura Rotundo1, Jonathan Filippi, Roberto Gobetto
1Department of Chemistry and NIS (Centre of excellence), University of Torino via P. Giuria 7, 10125 Torino, Italy. carlo.nervi@unito.it.
Abstract:
The organometallic complex (fac-Mn(apbpy)(CO)3Br) (apbpy = 4-(4-aminophenyl)-2,2'-bipyridine) grafted electrochemically onto carbon cloth serves as an electrocatalyst in the aqueous reduction of CO2 to syngas. A faradaic efficiency of around 60% for CO and 40% for H2 at -1.35 V is achieved together with a productivity rate higher than 870 NlCO h-1 gMn-1 at turnover numbers of up to 33 200 during 10 hours of operation.
More Related Videos
Related Concept Videos
What is an Electrochemical Gradient?
The chemical gradient relies on differences in the abundance of a substance on the outside versus the inside of a cell and flows from areas of high to low ion concentration. In contrast, the electrical gradient revolves around an...
Standard Electrode Potentials
The Carbon Cycle
Oxidation-Reduction Reactions
Carbon Skeletons
Water and Mineral Acquisition

