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Updated: Jan 31, 2026

Directed Assembly of Elastin-like Proteins into defined Supramolecular Structures and Cargo Encapsulation In Vitro
Published on: April 8, 2020
Size-selective encapsulation of C60 and C60-derivatives within an adaptable naphthalene-based tetragonal prismatic
Cristina García-Simón1, Alba Monferrer, Marc Garcia-Borràs
1Institut de Química Computacional i Catàlisi (IQCC) and Departament de Química, Universitat de Girona, Campus Montilivi, Girona, E-17003, Catalonia, Spain. cristina.simon@udg.edu miquel.costas@udg.edu xavi.ribas@udg.edu.
Abstract:
A novel naphthalene-based 5·(BArF)8 capsule allows for the size-selective inclusion of C60 from fullerene mixtures. Its size selectivity towards C60 has been rationalized by its dynamic adaptability in solution that has been investigated by molecular dynamics. Additionally, 5·(BArF)8 encapsulates C60-derivatives such as C60-PCBM and N-methylpyrrolidine-C60. The latter can be separated from C60 since 5·(BArF)8 displays distinct affinity for them.
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