Single-Step Electrospun Ir/IrO₂ Nanofibrous Structures Decorated with Au Nanoparticles for Highly Catalytic Oxygen...

Nanocomposites of gold (Au) and iridium (Ir) oxide with various compositions (denoted as Au _xIr_{1- x}O _y, x = 0.05, 0.10, or 0.33, Au precursor molar ratio to Ir precursor) were synthesized via electrospinning and subsequent calcination method with two different solvent composition ratios of ethanol to N, N-dimethylformamide (DMF) in the electrospinning solution (ethanol/DMF = 70:30 or 50:50% v/v). Simple single-step electrospinning successfully fabricated a hierarchical nanostructure having Au nanoparticles formed on fibrous main frames of Ir/IrO₂. Different solvent composition in the electrospinning solution induced the formation of main frames with distinct nanostructures; nanoribbons (Au _xIr_{1- x}O _y-70) with ethanol/DMF = 70:30; and nanofibers (Au _xIr_{1- x}O _y-50) with ethanol/DMF = 50:50. The pure Ir or Au counterparts (IrO _y and Au) were also prepared by the same synthetic procedure as Au _xIr_{1- x}O _y. Oxygen evolution reaction (OER) activities of as-synthesized Au _xIr_{1- x}O _y were investigated in 0.5 M H₂SO₄ and compared to those of IrO _y, Au, and commercial iridium (Ir/C, 20% Ir loading on Vulcan carbon). Among them, Au_0.10Ir_0.90O _y-50 exhibited the best OER activity, even better than previously reported catalysts containing both Ir and Au. The high OER activity of Au_0.10Ir_0.90O _y-50 was mainly attributed to the fiber frame structure and the optimal interfacial areas between Au and Ir/IrO₂, which are electrophilic OER active sites. The stability of Au_0.10Ir_0.90O _y-50 was also evaluated to be much higher than that of Ir/C during OER. The current study suggests that the presence of Au on the Ir/IrO₂ surface improves the OER activity of Ir/IrO₂.